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Fire Strength Performance of High Strength Concrete Structural Members
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Introduction What is "Spalling"? Mechanisms of Spalling
Why Spalling is a problem in HSC & not in Normal Strength Concrete (NSC) Factors affecting fire performance & ways to improve fire performance of High Strength Concrete Structural members
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Article based on contribution by: Mr Saransh Kataria & Mr Satyajeet Harne , Civil engineering Students, S.G.S.I.T.S, Indore
Spalling can be described as the breaking of layers or pieces of concrete from the surface of a structural element when it is exposed to the high and rapidly rising temperatures experienced in fires.
Why Spalling is a problem in HSC & not in Normal Strength Concrete (NSC)?

The conventional theory of explosive spalling is that it is chiefly caused by the build-up of water vapour pressure  in concrete during fire.  If the concrete is not very permeable, water vapour formed within it during heating will not be able to dissipate and pressure is formed.  When that pressure exceeds the tensile strength of the concrete, explosive spalling will result.

HSC is produced primarily through use of a relatively low water/cementitious ratio and incorporates silica fume. This leads to a reduced permeability relative to normal weight concretes

Because of the relatively high permeability of normal strength concrete, when subject to fire, water vapour is able to readily dissipate through it.  Vapour pressure within the concrete therefore remains within its tensile strength and spalling is generally avoided. 

Whereeas HSC is more susceptible to explosive spalling under fire conditions due to the buildup of pore pressure in the cement paste (due to its reduced permeability).

The extremely high water vapour pressure, generated during exposure to fire, cannot escape because of the high density (and low permeability) of HSC. This pressure often reaches the saturation vapour pressure, which at 300°C is about 8 MPa. Such internal pressures are often too high to be resisted by the HSC, which has a tensile strength of about 5 MPa.

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References:
1. "Fire Performance of High-Strength Concrete Structural Members" by V.K.R.Kodur
2.  "The effect of fire-Concrete Spalling"  from http://www.promat-tunnel.com
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