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The hydration starts at the
surface of cement particles. As such, it is the total surface area of cement
that represents the material available for hydration. The effect of
"fineness" of cement on various parameters is discussed below:
(i) Rate of hydration increases with fineness, leads to higher rate
of development of strength in initial period and heat generation.
(ii) Hydration takes place on the surface of cement particle. Finer
particles will be more completely hydrated.
(iii) Increasing fineness decreases the amount of bleeding but also requires
more water for workability which can result in an increase in dry shrinkage.
(iv) High fineness reduces the durability to freeze-thaw cycles.
(v) Increased fineness requires more gypsum to control setting as more C3A
is now available for early hydration.
Generally greater the fineness, greater is the rate of development of strength
during the initial period and larger is the heat evolution, This is possible
because greater fineness enables a larger surface of cement to come in contact
with water during the initial period, although the long term effect may not be
different.
In addition, the particle size also influences the hydration and strength at
various ages. Particles below 5 microns hydrate within 1 to 2 days and the
hydration of l0-25 micron sizes may commence only after 7 days.
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