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Quick lime is an unstable and slightly hazardous
product and therefore is normally ‘hydrated’ or ‘slaked’, by adding water, becoming not only more stable but also easier and
safer to handle.
The addition of water to
quicklime results in a great deal of heat being given off and the formation of
calcium hydroxide.
CaO
+ H2O ----------->
Ca(OH)2 +
Heat
Quicklime
Water
Calcium hydroxide
Traditionally, an excess of
water was added to quicklime and the material allowed to soak for several weeks
or even months in pits (the process called slaking).
Chemical analysis of historic
mortars indicates that many of these contain inclusions of lime that have
remained unmixed and unslaked during mortar production.
The ancient Greeks and Romans produced mortar
by burning limestone and slaking (mixing with water) the resultant product with
water and, then mixing it with sand. Currently the calcination of limestone is
generally undertaken in shaft or rotary kilns.
As time progressed the
process was refined and after the addition of water the mixture was passed over
a screen to remove particles which were reacting slowly. The mixture was then
left to mature for about a month prior to use. The inefficiency of this process
could lead to the expansion of some of
the unslaked particles resulting in popping and pitting of lime based plasters.
Expansion of the mortar could also take place, a phenomenon known as blowing.
The slaking of quicklime has
largely been superseded by modern methods of producing hydrated lime.
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