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Cement
soundness can be considered to be a resistance to, or the lack of, any swelling,
cracking, or disintegration resulting from an expansive chemical reaction
such as the hydration of free lime (CaO) or crystalline free magnesia (MgO) in
cement paste, mortar, or concrete.
A “Sound Cement”
basically is one which does not undergo a large change in volume, once it has
set.
Unsoundness of cement may cause disruption of the hardened cement paste
under conditions of restraint.
Unsoundness of cement occurs due to delayed /slow
hydration or other reaction of some compounds present in the hardened cement
viz. free lime, magnesia and calcium sulphate.
In
the United
States, the
Autoclave
expansion test (ASTM C 151) is used to provide an index of potential
delayed expansion caused by the hydration of CaO and MgO in hydraulic
cements. In other countries, cement soundness may be monitored by cement paste
expansion in boiling water with the Le
Chatelier test apparatus. However, the Le Chatelier procedure
determines unsoundness from the hydration of free CaO only, whereas the autoclave procedure measures cement paste
expansion from either free CaO, free MgO, or both.
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