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Why concrete fails at considerably lower stress than the strength of bulk paste or aggregate?
Concrete is generally considered as two phase material i.e paste phase & aggregate phase. There is also a third phase called the transition phase which represents the interfacial region between the particles of coarse aggregate & hardened cement paste. The interfacial zone is 10 to 50 mm in thickness.

Transition zone is a plane of weakness due to poorer bond between paste & aggregate , in general.

Transition zone develops microcracks due to drying shrinkage  or temperature variation even before the structure is loaded. When structure is loaded & at high stress levels, these micro cracks propagate and bigger cracks are formed resulting in failure of bond.

It is because of this presence of Transition zone  that concrete fails at considerably lower stress than the strength of bulk paste or aggregate.

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